Silver chloride

Silver chloride
Names
IUPAC name
Silver(I) chloride
Other names
Cerargyrite
Chlorargyrite
Horn silver
Argentous chloride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.121
RTECS number
  • VW3563000
UNII
CompTox Dashboard (EPA)
  • InChI=1S/Ag.ClH/h;1H/q+1;/p-1 Y
    Key: HKZLPVFGJNLROG-UHFFFAOYSA-M Y
  • InChI=1S/Ag.ClH/h;1H/q+1;/p-1
  • Key: HKZLPVFGJNLROG-UHFFFAOYSA-M
SMILES
  • Cl[Ag]
Properties
AgCl
Molar mass 143.32 g·mol−1
Appearance White solid
Density 5.56 g cm−3
Melting point 455 °C (851 °F; 728 K)
Boiling point 1,547 °C (2,817 °F; 1,820 K)
520 μg/100 g at 50 °C
1.77×10−10[1]
Solubility soluble in NH3, conc. HCl, conc. H2SO4, alkali cyanide, (NH4)2CO3, KBr, Na2S2O3;

insoluble in alcohol, dilute acids.

Magnetic susceptibility (χ)
−49.0·10−6 cm3/mol
2.071
Structure[2]
cubic
Fm3m (No. 225)
Lattice constant
a = 555 pm
Coordination geometry
Octahedral
Thermochemistry
Std molar
entropy (S298)
96 J·mol−1·K−1[3]
−127 kJ·mol−1[3]
Hazards
NFPA 704 (fire diamond)
2
0
0
Safety data sheet (SDS) Fischer Scientific, Salt Lake Metals
Related compounds
Other anions
silver(I) fluoride, silver bromide, silver iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Silver chloride is an inorganic chemical compound with the chemical formula AgCl. This white crystalline solid is well known for its low solubility in water and its sensitivity to light. Upon illumination or heating, silver chloride converts to silver (and chlorine), which is signaled by grey to black or purplish coloration in some samples. AgCl occurs naturally as the mineral chlorargyrite.

It is produced by a metathesis reaction for use in photography and in pH meters as electrodes.

  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. ^ S. Hull; D. A. Keen (1999). "Pressure-induced phase transitions in AgCl, AgBr, and AgI". Physical Review B. 59 (2). APS: 750–761. Bibcode:1999PhRvB..59..750H. doi:10.1103/PhysRevB.59.750. S2CID 123044752.
  3. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A23. ISBN 978-0-618-94690-7.