RDX

RDX
RDX crystal
Names
Preferred IUPAC name
1,3,5-Trinitro-1,3,5-triazinane
Other names
1,3,5-Trinitroperhydro-1,3,5-triazine
RDX
cyclonite, hexogen
1,3,5-Trinitro-1,3,5-triazacyclohexane
1,3,5-Trinitrohexahydro-s-triazine
Cyclotrimethylenetrinitramine
Hexahydro-1,3,5-trinitro-s-triazine
Trimethylenetrinitramine
hexolite[1]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.004.092
UNII
UN number 0072, 0391, 0483
CompTox Dashboard (EPA)
  • InChI=1S/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2 Y
    Key: XTFIVUDBNACUBN-UHFFFAOYSA-N Y
  • InChI=1/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2
    Key: XTFIVUDBNACUBN-UHFFFAOYAY
SMILES
  • C1N(CN(CN1[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-]
Properties
C3H6N6O6
Molar mass 222.117 g·mol−1
Appearance Colorless or yellowish crystals
Density 1.806 g/cm3[2]
Melting point 205.5 °C (401.9 °F; 478.6 K)
Boiling point 234 °C (453 °F; 507 K)
insoluble [3]
Explosive data
Shock sensitivity Low
Friction sensitivity Low
Detonation velocity 8750 m/s
RE factor 1.60
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive, detonates on contact with mercury fulminate,[3] highly toxic
GHS labelling:
Pictograms
Danger
Hazard statements
H201, H301, H370, H373
Precautionary statements
P210, P250, P280, P370, P372, P373, P501
NFPA 704 (fire diamond)
3
1
4
Flash point Explosive [3]
Lethal dose or concentration (LD, LC):
100 mg/kg
NIOSH (US health exposure limits):
PEL (Permissible)
none [3]
REL (Recommended)
TWA 1.5 mg/m3 ST 3 mg/m3 [skin][3]
IDLH (Immediate danger)
N.D.[3]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen,[4] among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive.[5] Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. It was used widely in World War II and remains common in military applications. It is lower performing and more toxic than modern replacements such as TKX-50. [6]

RDX is often used in mixtures with other explosives and plasticizers or phlegmatizers (desensitizers); it is the explosive agent in C-4 plastic explosive and a key ingredient in Semtex. It is stable in storage and is considered one of the most energetic and brisant of the military high explosives,[2] with a relative effectiveness factor of 1.60.

  1. ^ "Hexolite, CAS Number: 82030-42-0". Archived from the original on October 27, 2021. Retrieved April 8, 2021.
  2. ^ a b Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States). 1989.
  3. ^ a b c d e f NIOSH Pocket Guide to Chemical Hazards. "#0169". National Institute for Occupational Safety and Health (NIOSH).
  4. ^ "RDX explosive". britannica.com. Retrieved September 27, 2021.
  5. ^ Field, Simon Quellen (July 1, 2017). Boom!: The Chemistry and History of Explosives. Chicago Review Press. pp. 89–94. ISBN 978-1613738054.
  6. ^ Niko Fischer, Dennis Fischer, Thomas M. Klapötke, Davin G. Piercey, Jörg Stierstorfer (2012), "Pushing the limits of energetic materials – the synthesis and characterization of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate", Journal of Materials Chemistry, vol. 22, no. 38, pp. 20418–20422, doi:10.1039/C2JM33646D{{citation}}: CS1 maint: multiple names: authors list (link)