Ethylene
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| Names | |||
|---|---|---|---|
| Preferred IUPAC name
Ethene[1] | |||
| Systematic IUPAC name
Ethene | |||
| Other names
Refrigerant R-1150
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| Identifiers | |||
3D model (JSmol)
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Beilstein Reference
|
1730731 | ||
| ChEBI | |||
| ChEMBL | |||
| ChemSpider | |||
| ECHA InfoCard | 100.000.742 | ||
| EC Number |
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Gmelin Reference
|
214 | ||
| KEGG | |||
PubChem CID
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| RTECS number |
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| UNII | |||
| UN number | 1962 1038 | ||
CompTox Dashboard (EPA)
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SMILES
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| Properties | |||
| C 2H 4 | |||
| Molar mass | 28.054 g·mol−1 | ||
| Appearance | colourless gas | ||
| Density | 1.178 kg/m3 at 15 °C, gas[2] | ||
| Melting point | −169.2 °C (−272.6 °F; 104.0 K) | ||
| Boiling point | −103.7 °C (−154.7 °F; 169.5 K) | ||
| 131 mg/L (25 °C);[3] 2.9 mg/L[4] | |||
| Solubility in ethanol | 4.22 mg/L[4] | ||
| Solubility in diethyl ether | good[4] | ||
| Acidity (pKa) | 44 | ||
| Conjugate acid | Ethenium | ||
Magnetic susceptibility (χ)
|
−15.30·10−6 cm3/mol | ||
| Viscosity | 10.28 μPa·s[5] | ||
| Structure | |||
Molecular shape
|
D2h | ||
Dipole moment
|
zero | ||
| Thermochemistry | |||
Std molar
entropy (S⦵298) |
219.32 J·K−1·mol−1 | ||
Std enthalpy of
formation (ΔfH⦵298) |
+52.47 kJ/mol | ||
| Hazards | |||
| GHS labelling: | |||
Pictograms
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| Danger | |||
Hazard statements
|
H220, H336 | ||
Precautionary statements
|
P210, P261, P271, P304+P340, P312, P377, P381, P403, P403+P233, P405, P501 | ||
| NFPA 704 (fire diamond) | |||
| Flash point | −136 °C (−213 °F; 137 K) | ||
Autoignition
temperature |
542.8 °C (1,009.0 °F; 815.9 K) | ||
| Safety data sheet (SDS) | ICSC 0475 | ||
| Related compounds | |||
Related compounds
|
Ethane Acetylene Propene | ||
| Supplementary data page | |||
| Ethylene (data page) | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula C2H4 or H2C=CH2. It is a colourless, flammable gas with a faint "sweet and musky" odour when pure.[7] It is the simplest alkene (a hydrocarbon with carbon–carbon double bonds).
Ethylene is widely used in the chemical industry, and its worldwide production (over 150 million tonnes in 2016[8]) exceeds that of any other organic compound.[9][10] Much of this production goes toward creating polyethylene, which is a widely used plastic containing polymer chains of ethylene units in various chain lengths. Production emits greenhouse gases, including methane from feedstock production and carbon dioxide from any non-sustainable energy used.
Ethylene is also an important natural plant hormone and is used in agriculture to induce ripening of fruits.[11] The hydrate of ethylene is ethanol.
- ^ "Ethylene". Archived from the original on 2023-10-08. Retrieved 2021-05-27.
- ^ Record of Ethylene in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 25 October 2007.
- ^ McAuliffe, C. (1966). "Solubility in Water of Paraffin, Cycloparaffin, Olefin, Acetylene, Cycloolefin, and Aromatic Hydrocarbons". Journal of Physical Chemistry. 70 (4): 1267–1275. doi:10.1021/j100876a049.
- ^ a b c Neiland, O. Ya. (1990) Органическая химия: Учебник для хим. спец. вузов. Moscow. Vysshaya Shkola. p. 128.
- ^ Kestin J, Khalifa HE, Wakeham WA (1977). "The viscosity of five gaseous hydrocarbons". The Journal of Chemical Physics. 66 (3): 1132–1134. Bibcode:1977JChPh..66.1132K. doi:10.1063/1.434048.
- ^ ETHYLENE | CAMEO Chemicals | NOAA Archived 2015-04-02 at the Wayback Machine. Cameochemicals.noaa.gov. Retrieved on 2016-04-24.
- ^ Cite error: The named reference
UllmannEthylenewas invoked but never defined (see the help page). - ^ Research and Markets. "The Ethylene Technology Report 2016 - Research and Markets". www.researchandmarkets.com. Archived from the original on 10 May 2020. Retrieved 19 June 2016.
- ^ "Production: Growth is the Norm". Chemical and Engineering News. 84 (28): 59–236. July 10, 2006. doi:10.1021/cen-v084n034.p059.
- ^ Propylene Production from Methanol. Intratec. 2012-05-31. ISBN 978-0-615-64811-8. Archived from the original on 2016-03-04. Retrieved 2012-09-17.
- ^ Wang KL, Li H, Ecker JR (2002). "Ethylene biosynthesis and signaling networks". The Plant Cell. 14 (Suppl): S131-151. Bibcode:2002PlanC..14S.131W. doi:10.1105/tpc.001768. PMC 151252. PMID 12045274.