Ammonium

Ammonium
Names
IUPAC name
Ammonium ion
Systematic IUPAC name
Azanium[1]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
Gmelin Reference
84
KEGG
MeSH D000644
UNII
CompTox Dashboard (EPA)
  • InChI=1S/H3N/h1H3/p+1
    Key: QGZKDVFQNNGYKY-UHFFFAOYSA-O
  • InChI=1/H3N/h1H3/p+1
    Key: QGZKDVFQNNGYKY-IKLDFBCSAZ
SMILES
  • [NH4+]
Properties
[NH4]+
Molar mass 18.039 g·mol−1
Acidity (pKa) 9.25
Conjugate base Ammonia
Structure
Molecular shape
Tetrahedral
Related compounds
Other cations
  • Phosphonium [PH4]+
  • Arsonium [AsH4]+
  • Hydronium [H3O]+
  • Sulfonium [H3S]+
  • Fluoronium [H2F]+
  • Chloronium [H2Cl]+
  • Bromonium [H2Br]+
  • Iodonium [H2I]+
  • Carbonium [CH5]+
  • Trihydrogen cation [H3]+
Related compounds
Ammonium radical •NH4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) molecular ion with the chemical formula NH+4 or [NH4]+. It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (NH3). Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations ([NR4]+), where one or more hydrogen atoms are replaced by organic or other groups (indicated by R). Not only is ammonium a source of nitrogen and a key metabolite for many living organisms, but it is an integral part of the global nitrogen cycle.[2] As such, human impact in recent years could have an effect on the biological communities that depend on it.

  1. ^ International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSC–IUPAC. ISBN 0-85404-438-8. pp. 71,105,314. Electronic version.
  2. ^ Schlesinger, William H.; Bernhardt, Emily S. (2020-01-01), Schlesinger, William H.; Bernhardt, Emily S. (eds.), "Chapter 12 - The Global Cycles of Nitrogen, Phosphorus and Potassium", Biogeochemistry (Fourth Edition), Academic Press, pp. 483–508, doi:10.1016/b978-0-12-814608-8.00012-8, ISBN 978-0-12-814608-8, retrieved 2024-03-08